Ether

An ether has an oxygen atom bonded to two carbons via single bonds — unlike an alcohol, the ether's oxygen carries no hydrogen at all. They're generally unreactive, which is why they're widely used as solvents.

General formula

R–O–R'

Naming rule

Systematic name = [smaller radical]-oxy + [larger radical chain]-ane (e.g., methoxyethane). The functional class name (ethyl ether, methyl ethyl ether) is also widely accepted.

How to name it with IUPAC

Use this sequence to move from the structure to the systematic name:

  1. Choose the larger carbon chain as the parent.
  2. Turn the smaller side into an alkoxy prefix and name the larger chain.
  3. CH₃OCH₂CH₃ = methoxyethane: methoxy + ethane.
CH₃OCH₂CH₃ = methoxyethane: methoxy + ethane.

Examples

NameFormula
Methoxyethane (methyl ethyl ether)CH₃–O–C₂H₅
Ethoxyethane (ethyl ether)C₂H₅–O–C₂H₅

Visual examples

See how the functional group appears inside the chain. Compare the drawings with the formulas in the table to practice visual recognition.

ROR
Schematic representation: R indicates the remaining carbon chain.

Chemical reading

Oxygen lies between two carbons and has no attached H. Ethers accept hydrogen bonds but do not donate them; many are volatile and flammable.

Properties and applications

Diethyl ether is a classic solvent and THF is a common cyclic ether; some ethers form hazardous peroxides during storage.

R–O–R′–O–
The structural group that defines this organic function.
Build a ether in the simulator →